Surfactants and Adsorption Calorimetry
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Adsorption of surfactants and organic pollutants at solid/liquid interfaces.
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Adsorption (batch and HPLC methods) and isotherm microcalorimetry
(immersion, titration and flow methods).
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Solids: Graphitised carbon, silica gel, controlled pore glass, clay
minerals.
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Solutes: cationic, anionic and nonionic surfactants; alcohol and
phenol derivatives.
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Surface modifications and XRD measurements of smectite clays. Intercalation
and adsolubilization.
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Interfacial thermodynamics (Gibbs energy, enthalpy and entropy functions).
Materials Science and Catalysis
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Preparation of tranistion metal nanoparticles in liquid media and on solid
supports
(control of size and shape).
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Metals: Pd, Pt, Pd/Pt, Rh.
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Supports: layer-structured materials. Graphite, cationic and anionic
clays
(montmorillonite, hydrotalcite-type materials).
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Characterization of transition metal catalysts (TEM, XRD, SAXS, PCS).
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Calorimetric investigations of metal/hydrogen interactions (gas sorption
calorimetry).
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Liquid-phase hydrogenation of alkenes and alkynes (activity and selectivities).
Previous Research Experience
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Stability of Stöber silica particles in mixed solvent media (TEM,
SAXS, PCS, low-shear rheology).
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High-vacuum anionic polymerization. Diblock copolymers in organic solvents
and in polymer melts
(IR, NMR, PFGSE NMR).
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